Properties of two-component nematic liquid crystal mixtures in the range of 0.3–3.0 THz

TeraView's TPS Spectra 3000 was used to investigate nematic liquid crystals in the range of 0.3–3.0 THz.


http://www.tandfonline.com/doi/abs/10.1080/02678292.2015.1036816#.VYvdFvlViko


Abstract

In this work, we present the results of terahertz measurements of five nematic liquid crystal materials. Optical properties like refractive indices, birefringence and absorption coefficients of liquid crystals (LCs) for ordinary and extraordinary polarisation were compared. The aim of this study was to check the impact of the structure of LC molecules on above properties. The compounds with different core structure and various number of laterally substituted fluorine atoms were chosen. A standard terahertz Time-Domain Spectrometer to measurements from 0.3 THz to 3 THz was used.

Impact of Pellet Thickness on Quantitative Terahertz Spectroscopy of Solid Samples in a Polyethylene Matrix

Anal. Chem., 2013, 85 (7), pp 3674–3681
DOI: 10.1021/ac302017d
Publication Date (Web): February 25, 2013
Copyright © 2013 +American Chemical Society

Authors: Hankyu Namkung †, Jaejin Kim †, Hoeil Chung *†, and Mark A. Arnold *‡
† Department of Chemistry and Research Institute for Natural Sciences, Hanyang University, Seoul, Korea 133-791
‡ Department of Chemistry and Optical Science and Technology Center, University of Iowa, Iowa City Iowa 52242, United States

Abstract

Pellets composed of different weight-percent (wt-%) of lactose within a polyethylene (PE) matrix are used to examine how the physical thickness of solid samples impact analytical measurements performed over terahertz (THz) frequencies when using time-domain THz spectroscopy. Results indicate that the thickness of each pellet depends on the mass and physical properties of the individual components that comprise the pellet. Thickness of mixture pellets depends on the porosity of the individual pellet components. Porosity measurements presented here for PE and lactose give values of 25.6 ± 0.3 and 14.5 ± 0.1, respectively, which indicate that more air is trapped within the compressed PE matrix compared to that for lactose. This difference in porosity creates different pellet thicknesses for pellets of the same nominal mass but with different relative amounts of PE and lactose. For this binary matrix, the thickness of each pellet is found to be a linear combination of the compressed densities of the individual components. Analysis of the time-domain THz spectra reveals that thinner samples are confounded by a fringe pattern observed in the frequency-domain spectra. This fringe pattern is created by an etalon corresponding to the air/pellet interfaces for the sample in the optical path. Spectra collected from thicker pellets are confounded by a sloping baseline caused by scattering effects within the pellet matrix. The quantitative impact of pellet thickness is determined by comparing the mean standard error of calibration (MSEC) and mean standard error of prediction (MSEP) for a set of leave-three-out cross validation multivariate calibration models based on the partial least-squares (PLS) algorithm. Results indicate that PLS models are capable of analytical measurements with MSEC and MSEP values between 0.04 and 0.20 wt-%. Analysis of spectral variance captured within the corresponding spectral loadings for each model indicates that spectral variance is lowest for the 300 mg samples where the impact of scattering is minimal under conditions when the sample etalon is nonexistent.

... Each time domain spectrum was collected with a TPI Spectra 1000 spectrometer (TeraView, Cambridge, UK) with a resolution setting of 1.2 cm-1. A detailed description of the instrumentation can ...