Wednesday, 11 January 2017

Preparation, characterization, Raman, and terahertz spectroscopy study on carbon nanotubes, graphene nano-sheets, and onion like carbon materials

A. Abouelsayed ; Badawi Anis ; Safwat Hassaballa ; Ahmed S.G. Khalil ; Usama M. Rashed ; Kamal A. Eid ; Emad Al-Ashkar ; W. El hotaby


We present the optical properties of carbon nanotubes, graphene nanosheets, and onion like carbon (OLC) samples with different cages size in wide frequency range from 0.06 to 1650 THz. The samples were characterized by high resolution transmission electron microscope (HRTEM), Raman, and UV–Vis-IR-THz spectroscopy. The broad absorption bands centered at around 10, 3, 2.5, 1.5, and 1.8 THz for SWCNTs, MWCNTs, graphene nanosheets, large cages (OLC1), and small cages (OLC2) samples, respectively, are assigned to plasmon resonance due to the localization of free carriers in a finite length. For SWCNTs, both the plasmon band position and the Drude weight (D) are located at higher values as compared with MWCNTs, graphene nanosheets, and OLC sample, suggesting that the dimensionality of the system plays a major role regarding the carrier mobility of the graphene structure. The differences in the estimated values of D, the Fermi energy (Ef), and density of carriers (N) in case of OLC samples can be due to the variation in sizes of the cages and the variation of the defects in the structure of the outermost layers of cages, where each cages consist of multi-layers of graphene enclosed one into another.

Full article available here.